1,1-Difluoro-N-phenyl-1-(phenylsulfonyl)methanesulfenamide

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem SID
Reaxys RN
(Benzenesulfonyl)difluoromethanesulfenamide ,PhSO2BB12H
Difluoromethylating Reagents
KUM2F38
1888317-24-5


29308692
image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay(Analysis Method)
Appearance
Boiling Point
Packaging
Storage
1,1-Difluoro-N-phenyl-1-(phenylsulfonyl)methanesulfenamide
C13H11F2NO2S2
315.36
≥95%(GC)
Brown Liquid
401±55ºC
5ml,10ml,50ml,100ml,500ml and 1L
Store at room temperature
(Benzenesulfonyl)difluoromethanesulfenamide (PhSO2BB12H) is a new shelf-stable eletronphilic reagent for direct introduction of PhSO2CF2S group,which is a valuable substituent with specific properties which can provide access to new applications of fluoroalkylthiolated compounds. Furthermore, mild magnesium-mediated reduction of the PhSO2CF2S group leads to a facile synthesis of difluoromethylthiolated molecules and their deuterated analogs.
Direct Electrophilic (Benzenesulfonyl)Difluoromethylthiolation with a Shelf-Stable Reagent. [1]
An easier and quicker access to (benzenesulfonyl)difluoromethanesulfenamide reagent. [2]
References:
[1] E. Ismalaj, D. Le Bars, T. Billard, Angew. Chem. Int. Ed. Engl., 2016, 55(15), pp 4790-4793.
[2] E. Ismalaj, T. Billard, J. F. Chem., 2017, 203, pp 215-217.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
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