(Benzenesulfonyl)difluoromethanesulfenamide (PhSO2BB12H) is a new shelf-stable eletronphilic reagent for direct introduction of PhSO2CF2S group,which is a valuable substituent with specific properties which can provide access to new applications of fluoroalkylthiolated compounds. Furthermore, mild magnesium-mediated reduction of the PhSO2CF2S group leads to a facile synthesis of difluoromethylthiolated molecules and their deuterated analogs.
Direct Electrophilic (Benzenesulfonyl)Difluoromethylthiolation with a Shelf-Stable Reagent.
An easier and quicker access to (benzenesulfonyl)difluoromethanesulfenamide reagent.
 E. Ismalaj, D. Le Bars, T. Billard, Angew. Chem. Int. Ed. Engl., 2016, 55(15), pp 4790-4793.
 E. Ismalaj, T. Billard, J. F. Chem., 2017, 203, pp 215-217.
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