A much milder nucleophilic difluoromethylating reagent than difluoromethyl phenyl sulfone. Difluoro(phenylsulfonyl)methyl can be transferred to aldehydes, ketones, alkyl halides, and non-activated imines, under the action of lewis bases such as tetrabutylammonium triphenyldifluorosilicate(TBAT), potassium fluoride, potassium hydrodifluoride, and potassium carbonate.
Stereoselective synthesis of α-difluoromethyl-β-amino alcohols via nucleophilic difluoromethylation with Me3SiCF2SO2Ph.
Nucleophilic (phenylsulfonyl)difluoromethylation of alkyl halides using PhSO2CF2SiMe3 Preparation of gem-difluoroalkenes and trifluoromethyl compounds.
Reactions of sulfur- and phosphorus-substituted fluoroalkylating silicon reagents with imines and enamines under acidic conditions.
 L.Li, C. Ni, F.Wang, J. Hu, Tetrahedron Lett.,2008, 49(10), pp 1605-1608.
 L.Zhu, Y.Li, Y. Zhao, J. Hu, Tetrahedron Lett., 2010,51(47), pp 6150-6152.
 M.D.Kosobokov, A.D.Dilman, M. I. Struchkova, P.A. Belyakov,J.Hu, J. Org. Chem., 2012,77(4),pp 2080-2086.
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