[[(ethoxycarbonyl)difluoromethyl]thio]phthalimide is a new,easily-scalable,shelf-stable and efficient eletrophilic difluoromethylthiolating reagent, which reacts with electron-richheteroarenes/arenes, β-ketoesters, oxindoles, benzofuranones, and thiols. More importantly, the ethoxycarbonyl group of the resulting fluoroalkylthiolated compounds could be easily converted into various other functional groups such as chloride, alkynyl, hydrocarbonyl, carbomoyl, hydromethyl, or heteroaryl groups.
[[(Ethoxycarbonyl)difluoromethyl]thio]phthalimide: A Shelf-Stable, Electrophilic Reagent with a Convertible Group for the Synthesis of Diversified Fluoroalkylthiolated Compounds.
 F. Shen, P. Zhang, L. Lu, Q. Shen, Org. Lett., 2017, 19(5), PP1032-1035.
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