N-[(diethylphosphonodifluoromethyl)sulfanyl]-2,4,6-trimethylaniline(MesNHSCF2PO(OEt)2) is a unique bench-stable and easy-to-handle electrophilic reagent for difluoromethylthiolation, under which the SCF2PO(OEt)2 Group can be introduced to various nucleophiles, such as primary and secondary amines, aromatic and aliphatic thiols.
An Electrophilic Reagent for the Direct Introduction of the SCF2PO(OEt)2 Group to Molecules.
 H.Y.Xiong, X. Pannecoucke, A. Bayle, T. Besset, Angew. Chem., 2016, 55(43), pp 13490-13494.
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