S-(difluoromethyl) benzenesulfonothioate(also named as PhSO2SCF2H) is a powerful reagent for radical difluoromethylthiolation of aryl and alkyl boronic acids, decarboxylative difluoromethylthiolation of aliphatic acids, and a phenylsulfonyl‐difluoromethylthio difunctionalization of alkenes under mild reaction conditions.
PhSO2SCF2H: A Shelf-Stable, Easily Scalable Reagent for Radical Difluoromethylthiolation. 
Atom Transfer Radical Addition to Alkynes and Enynes: A Versatile Gold/Photoredox Approach to Thio-Functionalized Vinylsulfones. 
Radical difluoromethylthiolation of aromatics enabled by visible light. 
Synthesis of Difluoromethylthioesters from Aldehydes.