Chlorodimethyl(pentafluorophenyl)silane

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem CID
Reaxys RN
Flophemesyl chloride,Pentafluorophenyldimethylsilyl chloride
Fluorinated Building Blocks
KUMI5F32
20082-71-7
MFCD00000500
88361
2858407
image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay
Appearance
Boiling Point
Packaging
Storage
Chlorodimethyl(pentafluorophenyl)silane
C8H6ClF5Si
260.67
≥98.0%
Colorless Clear Liquid
88-90ºC/10mm Hg
5g,10g,50g,100g,500g and1kg
Moisture sensitive. Store away from strong bases, water/moisture and oxidizing agents
Chlorodimethyl(pentafluorophenyl)silaneIt is used as a gas chromatography (GC) derivatization reagent for detection of sterols at low concentration as flophemesyl derivatives, which are readily detected by electron capture. It also can employed for surface modification of  TiO2 nanotubes (TNTs) to control drug release.
Formation of pentafluorophenyldimethylsilylethers and their use in the gas chromatographic analysis of sterols. [1]
Flophemesyl derivatives of alcohols, phenols, amines and carboxylic acids and their use in gas chromatography with electron-capture detection. [2]
Reactions of methyl(pentafluorophenyl)- and methyl(pentafluorophenyl)phenylsilanes with electrophiles. A convenient preparative route to halogeno(methyl)pentafluorophenylsilanes C6F5SiMe2X and C6F5SiMeX2 (X=F, Cl and Br). [3]
Recent advances on smart TiO2 nanotube platforms for sustainable drug delivery applications. [4]
References:
[1] E.D.Morgan,et al,  J.Chromatogr. A., 1975, 104(2), pp351-358.
[2] A.J.Francis,et al,  J.Chromatogr. A., 1978, 1(21), pp111-117.
[3] H.J.Frohna,A.Lewina,V.V.Bardinb, J.Organometallic Chem., 1998, 570(2), pp255-263.
[4] Q.Wang, J.Y.Huang, H.Q.Li, A.Z.J.Zhao, Y.Wang, K.Q.Zhang, H.T.Sun, Y.K.Lai, Int. J. Nanomedicine, 2017, 12, pp151-156.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
Legal Information
Danger
H314
P260,P303+P361+P353,P305+P351+P338,P301+P330+P331

UN 2987 8/PG II

1. Product Specification
2. Safety Data Sheet
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