N,N-diethyl-α,α-difluoro-(m-methylbenzyl)amine

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem CID
Reaxys RN
N,N-Diethyl-alpha,alpha-difluoro-3-methylbenzylamine,DFMBA
Fluorinating Reagents
KUM2F33
500131-50-0
MFCD12031321
11820531
9697603
image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay
Appearance
Boiling Point
Packaging
Storage
N,N-diethyl-α,α-difluoro-(m-methylbenzyl)amine
C12H17F2N
213.27
≥97.0%(GC)
Colorless Liquid
84-85°C(5 Torr)
1g,5g,10g,20g,50g,100g and 500g
Store at room temperature
DFMBA is a deoxy-fluorinating agent,which can be reacted with various oxygen containing functional groups, such as alcohols, epoxides, aldehydes, etc., to provide the corresponding fluorinated species. 
Selective synthesis of fluorinated carbohydrates using N,N-diethyl-α, α-difluoro-(m-methylbenzyl)amine. [1]
Synthesis of gem-difluorides from aldehydes using DFMBA. [2]
Selective monofluorination of diols using DFMBA. [3]
References:
[1] S.Kobayashi,et al, Tetrahedron Lett., 2004, 45(6), pp 1287-1289.
[2] T.Furaya, et al, J. F. Chem., 2005, 126(5), pp 721-725.
[3] A. Yoneda, et al, Chem. Commun., 2005, 28, pp 3589-3590.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
Legal Information
Danger
H314
P260,P305+P351+P338,P303+P353+P361

UN 2735 8 /PG III

1. Product Specification
2. Safety Data Sheet
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