DMPU-HF Reagent

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem SID
Reaxys RN
DMPU-HF Complex, N,N'-Dimethylpropyleneurea Hydrofluoride (HF 65%)
Fluorinating Reagents
KUMI1F13
287966-55-6
MFCD19690901
329768755
28838644
image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay(HF content)
Appearance
Boiliing Point
Packaging
Storage
DMPU-HF Reagent
C6H13FN2O
148.18
65-69%
Liquid

5ml,10ml and 50ml
Store 2-8°C(recommended)
DMPU-HF reagent is utilizing Hydrogen Fluoride in a convenient way for fluorination of alkynes, fluorination of aziridines, and fluoro-prins reaction. Compared to TREAT-HF and Olah′s Reagent, DMPU-HF is more tolerant of transition metals due to the reduced basicity of DMPU, compared to Triethylamine and Pyridine.
Designer HF-Based Fluorination Reagent: Highly Regioselective Synthesis of Fluoroalkenes and gem-Difluoromethylene Compounds from Alkynes.[1]
Preparation of Fluorinated Tetrahydropyrans and Piperidines using a New Nucleophilic Fluorination Reagent DMPU/HF.[2]
Achieving regio- and stereo-control in the fluorination of aziridines under acidic conditions.[3]
References:
[1] O. E. Okoromoba, J. Han, G. B. Hammond, B. Xu, J. Am. Chem. Soc., 2014, 136(41), pp 14381-14384.
[2] O. E. Okoromoba, G. B. Hammond, B. Xu, Org. Lett., 2015, 17(16), pp 3975-3977.
[3] O. E. Okoromoba, Z. Li, N. Robertson, M. S. Mashuta, U. R. Couto, C. F. Tormena, B. Xu, G. B. Hammond, Chem. Commun., 2016, 52(91) pp13353-13356.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
Legal Information
Danger
H300+P310+P330,H314
P260,P262,P264,P270,P271,P280,P284,P301+P330+P331+P310
2933.59.9500
UN 2927 8(6.1)/PG I

1. Product Specification
2. Safety Data Sheet
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