Fluorotris(triphenylphosphine)copper(I)

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem CID
Reaxys RN
(PPh3)3CuF
Trifluoromethylating Reagents
KUMI1F04
25753-74-6
MFCD12546045
71310837
17198416
image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay
Appearance
Melting Point
Packaging
Storage
Fluorotris(triphenylphosphine)copper(I)
C54H45CuFP3
869.42
≥95%(NMR)
White to Brown Solid
144-157°C
5g,10g,50g,100g,200g and 500g
Store at room temperature
Fluorotris(triphenylphosphine)copper(I) (also known as (PPh3)3CuF) is a useful reagent for fluorination of allyl chlorides, hydrofluorination of Ynamides and ketones, hydrosilation of ketones and borylsatnnylation of alkynes.
Mechanism of ketone hydrosilylation by Cu(I) catalysts: A theoretical study. [1]
Regio- and Stereoselective Allylic Trifluoromethylation and Fluorination using CuCF3 and CuF Reagents. [2]
Cu(I)- or Ag(I)-Catalyzed Regio- and Stereocontrolled trans-Hydrofluorination of Ynamides. [3]
Copper-Catalyzed Borylstannylation of Alkynes with Tin Fluorides. [4]
Comparative profiling of well-defined copper reagents and precursors for the trifluoromethylation of aryl iodides. [5]
References:
[1] T.Gathy. et al, J. Organomet., 2009, 694(24), pp 3943-3950.
[2] J.M.Larsson, et al, J. Org. Chem., 2013, 78(14), pp 7330-7336.
[3] G.He. et al, Org. Lett., 2016, 18(8), pp 1856-1859.
[4] H.Yoshida, et al, Organometallics, 2017, 36(7), pp 1345-1351.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
Legal Information
Warning
H315,H319,H335
P261,P305+P351+P338
2931399090
NONH for all modes of transport

1. Product Specification
2. Safety Data Sheet
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