Triethylamine trihydrofluoride

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem SID
Reaxys RN
Hydrogen fluoride triethylamine, TREAT-HF
Fluorinlating Reagents
KUMI3F15
73602-61-6
MFCD00043294
87577703
5522945
image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay(Analysis Method)
Appearance
Boiling Point
Packaging
Storage
Triethylamine trihydrofluoride
C₆H₁₈F₃N
161.21
≥98%
Colorless to Pale yellow Liquid
70°C/15 mmHg(lit.)
5g,10g,25g,50gl,100g,500g,1kg,5kg and 25kg
Store at room temperature
Triethylamine trihydrofluoride(TREAT-HF) is a mild and selective reagent that has been used in the fluorination of a wide variety of compounds. such as, Preparation of vicinal difluorides from epoxides; synthesis of 3-fluoroazetidine,  Preparation of positron emission tomography (PET) probe (3,4-dihydroxy-6-[(18)F]fluoro-L-phenylalanine), etc..
Synthesis of 3-Fluoroazetidines. [1]
An easy access to fluoroalkanes by deoxygenative hydrofluorination of carbonyl compounds via their tosylhydrazones. [2]
Electrochemical nucleophilic synthesis of di-tert-butyl-(4-[18F]fluoro-1,2-phenylene)-dicarbonate. [3]
References:
[1] W.V.Brabandt, et al, J. Org. Chem.,  2006, 71 (18), pp 7100–7102
[2] A.K.Yadav, et al, Chem. Commun., 2013, 49(21), pp 2154-2156.
[3] Q.He, Y.Wang, et al, Appl. Radiat. Isot., 2014, 92, pp 2-57.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
Legal Information
Danger
H290,H314,H300+H310+H330
P201,P202,P234,P260,P264,P270,P271,P273,P280,P303+P361+P353,P304,P340,P310
2921.19.1100
UN 2927 8(6.1)/PG I

1. Product Specification
2. Safety Data Sheet
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