3-Nitrophenylsulfur Pentafluoride

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem CID
Reaxys RN
3-(Pentafluorosulfur)-nitrobenzene
Pentafluorosulfanylated Building Blocks, API & Intermediates
KUMI5F20
2613-26-5
MFCD00221621
2775738
2699206
image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay
Appearance
Boiling Point
Packaging
Storage
3-Nitrophenylsulfur Pentafluoride
C6H4F5NO2S
249.16
≥98.0%
Colorless to Light Yellow Liquid
83-84°C/2.2mmHg
5g,10g,50g,100g,500g and 1kg
Store at room temperature
3-Nitrophenylsulfur Pentafluoride is a useful building block that commonly used in the preparation of various pentafluorosulfanyl (SF5) compounds.
Hydroxylation of nitro-(pentafluorosulfanyl)benzenes via vicarious nucleophilic substitution of hydrogen. [1]
Preparation of SF5 aromatics by vicarious nucleophilic substitution reactions of nitro(pentafluorosulfanyl)benzenes with carbanions. [2]
SNAr reactions of nitro-(pentafluorosulfanyl)benzenes to generate SF5 aryl ethers and sulfides. [3]
Highly selective synthesis of (E)-alkenyl-(pentafluorosulfanyl)benzenes through Horner-Wadsworth-Emmons reaction. [4]
Pd-catalyzed direct arylation of nitro(pentafluorosulfanyl)benzenes with aryl bromides. [5]
References:
[1] P.Beier, et al, Tetrahedron Lett., 2011, 52(34), pp 4392-4394.
[2] P.Beier, et al, J. Org. Chem., 2011, 76(11), pp 4781-4786.
[3] P.Beier, et al, Org. Lett., 2011, 13(6), pp 1466-1469.
[4] G.Lakobson, et al, Beilstein J. Org. Chem., 2012, 8, pp 1185-1190.
[5] C.Wang, et al, Org. Lett., 2013, 15(19), pp 5004-5007.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
Legal Information
Warning
H302,H319,H332,H335
P261,P305+P351+P338
2930909899
NONH for all modes of transport

1. Product Specification
2. Safety Data Sheet
Please inquire for pricing and availability of this product by writing email to sales@kumidas.com.