1-Chloro-1,2-benziodoxol-3(1H)-one

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem SID
Reaxys RN
1-chloro-1λ^{3},2-benziodoxol-3-one,NSC 191950
Non-Fluorochemicals
KUMI0F04
59457-26-0
 
329765696
141400
image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay
Appearance
melting Point
Packaging
Storage
1-Chloro-1,2-benziodoxol-3(1H)-one
C7H4ClIO2
282.46
≥98.0%(HPLC)
White to Light yellow Powder
167-170ºC
5g,10g,20g,50g,100g and 500g
Store at room temperature
1-Chloro-1,2-benziodoxol-3(1H)-one is used for hypervalent iodine reagent for oxidation reactions. It also is employed as precursor for synthesis of the hypervalent iodine-CF3 reagent(Togni II) for eletrophilic trifluoromethylation.
Preparation and X-ray crystal study of benziodoxaborole derivatives: new hypervalent iodine heterocycles. [1]
One-Pot Synthesis of Hypervalent Iodine Reagents for Electrophilic Trifluoromethylation. [2]
References:
[1] V.N.Nemykin, A.V.Maskaev, M.R.Geraskina,M.S.Yusubov, U.V.Zhdankin, Inorg. Chem., 2011, 50(12), pp 11263-11272.
[2] V.Matousek, E.Pietrasiak, R.Schwenk, A.Togni, J. Org. Chem., 2013, 78(3), pp 6763-6768.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
Legal Information
Warning
H315,H319,H335
P280,P305+P351+P338,P337+P313

NONH for all modes of transport

1. Product Specification
2. Safety Data Sheet
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