1-chloro-1,3-dihydro-3,3-dimethyl-1,2-benziodoxole

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem CID
Reaxys RN
1-chloro-3,3-dimethyl-1λ^{3},2-benziodoxole
Non-Fluorochemicals
KUMI0F03
69352-04-1
MFCD21648251
12494637
1074030
image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay
Appearance
melting Point
Packaging
Storage
1-chloro-1,3-dihydro-3,3-dimethyl-1,2-benziodoxole
C9H10ClIO
296.54
≥98.0%(HPLC)
Off-white to Yellow Powder
148-150ºC
5g,10g,20g,50g,100g and 500g
Store at room temperature
1-chloro-1,3-dihydro-3,3-dimethyl-1,2-benziodoxole is used for hypervalent iodine reagent for oxidation reactions. It also is employed as precursor for synthesis of the hypervalent iodine-CF3 reagent(Togni I) for eletrophilic trifluoromethylation.
Preparation and X-ray crystal study of benziodoxaborole derivatives: new hypervalent iodine heterocycles. [1]
One-Pot Synthesis of Hypervalent Iodine Reagents for Electrophilic Trifluoromethylation. [2]
References:
[1] V.N.Nemykin, A.V.Maskaev, M.R.Geraskina,M.S.Yusubov, U.V.Zhdankin, Inorg. Chem., 2011, 50(12), pp 11263-11272.
[2] V.Matousek, E.Pietrasiak, R.Schwenk, A.Togni, J. Org. Chem., 2013, 78(3), pp 6763-6768.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
Legal Information
Warning
H317,H319
P280,P305+P351+P338

NONH for all modes of transport

1. Product Specification
2. Safety Data Sheet
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