Tris[2-(dimethylamino)ethyl]amine

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem SID
Reaxys RN
Me6TREN
Non-Fluorochemicals, Acyclic Building Blocks, Non-Fluorinated Ligands
KUMI0F02
33527-91-2
MFCD00015607
253659833
1758212
image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay
Appearance
Boiling Point
Packaging
Storage
Tris[2-(dimethylamino)ethyl]amine
C12H30N4
230.39
≥98.0%(GC)
Colorless to Yellow Liquid
254-256ºC
5g,10g,20g,50g,100g and 500g
Store at room temperature
Tris[2-(dimethylamino)ethyl]amine (Me6TREN) is employed as Atom Transfer Radical Polymerization (ATRP) ligand for the creation of telechelic polymers. The metal complex based on  this N-containing ligand and cooper is the second often used catalyst in small amounts for ATRP without tedious purification to remove catalyst from final product.
Activators Regenerated by Electron Transfer for Atom Transfer Radical Polymerization of Styrene. [1]
Synthesis of high molecular weight poly(styrene-co-acrylonitrile) copolymers with controlled architecture.  [2]
Diminishing catalyst concentration in atom transfer radical polymerization with reducing agents. [3]
Use of ascorbic acid as reducing agent for synthesis of well-defined polymers by ARGET ATRP. [4]
ATRP for Everyone: Ligands and Initiators for the Clean Synthesis of Functional Polymers. [5]
References:
[1] W.Jakubowski, K.Min, K. Matyjaszewski, Macromolecules, 2006, 39(1), pp 39-45.
[2] J.Pietrasilk, H.Dong, K. Matyjaszewski, Macromolecules, 2006, 39(19), pp 6384-6390.
[3] K.Matyjaszewski, W.Jakubowski, K.Min, W.Tang, J. Huang, W.A.Braunecker, N.V.Tsarevsky, Proc. Natl. Acad. Sci. U.S.A., 2006, 103(42), pp 15309-15314.
[4] K.Min., H.Gao, K. Matyjaszewski, Macromolecules, 2007, 40(6), pp 1789-1791.
[5] W. Jakubowski, N.V.Tsarevsky, P. McCarthy, Material Matters, 2010, 5(1), pp 16-24.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
Legal Information
Danger
H314
P280,P305+P351+P338,P310
2921.29.0055
NONH for all modes of transport

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