4-Chlorophenyl Chlorothioformate

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem CID
Reaxys RN
Chlorothioformic Acid O-(4-Chlorophenyl) Ester
Nonfluorochemicals
KUMI0F347
937-64-4
MFCD00014465
70306
1565729
image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay
Appearance
Boiling Point
Packaging
Storage
4-Chlorophenyl Chlorothioformate
C7H4Cl2OS
207.08
≥98%
Pale Yellow to Deep Yellow Liquid
87°C/9mmHg
5g,10g,20g,50g,100g,500g,1kg and 25kg
Store at 2-8°C temp.
4-Chlorophenyl Chlorothioformate (also named as Chlorothioformic Acid O-(4-Chlorophenyl) Ester) is a useful building block for the preparation of various target compounds, e.g. Isothiocyanates.
Aminolysis of aryl chlorothionoformates with anilines in acetonitrile: Effects of amine nature and solvent on the mechanism. [1]
Nucleophilic substitution reactions of O-Aryl N-phenyl thioncarbamates with benzylamines in acetonitrile. [2]
Synthesis of Isothiocyanates by Reaction of Amines with Phenyl Chlorothionoformate via One-Pot or Two-Step Process. [3]
References:
[1] H.K.Oh, et al, J. Org. Chem., 2004, 69(24), pp 8219-8223.
[2] H.K.Oh, et al, Bull. Korean Chem. Soc., 2012, 33(17), pp 2427-2430.
[3] Z.Li, et al, Synthesis, 2013, 45, pp 1667-1674.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
Legal Information
Danger
H314
P280,P305+P351+P338,P310
2930909899
UN 3265 8/PG II

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