Methoxycarbonylsulfenyl chloride

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem CID
Reaxys RN
Methyl chlorosulfanylformate, S-Chloro O-methyl thiocarbonate
Nonfluorochemicals, Thiocarboxylating Reagent
KUMI0F346
26555-40-8 
MFCD00013648
1849980
506318
image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay
Appearance
Boiling Point
Packaging
Storage
Methoxycarbonylsulfenyl chloride
C2H3ClO2S
126.56
≥98%
Pale Yellow to Deep Yellow Liquid
133-134°C
5g,10g,20g,50g,100g,500g,1kg and 25kg
Store at 2-8°C temp.
Methoxycarbonylsulfenyl chloride (also named as Methyl chlorosulfanylformate, S-Chloro O-methyl thiocarbonate) is previously used as a thiocarboxylating reagent. Recently it is typically employed in the preparation of 3-[(methoxycarbonyl)dithio]-L-alanine and 3-2 pyridinyldithio propanoic acid hydrazide (PDPH,an important heterobifunctional crosslinker).
Synthesis and structure determination of N‐(alkoxycarbonylsulfenyl)‐s‐triazine herbicides. [1]
Nonvolatile S-alk(en)ylthio-L-cysteine derivatives in fresh onion (Allium cepa L. cultivar). [2]
A simple and efficient synthesis of 3-2 pyridinyldithio propanoic acid hydrazide: A heterobifunctional crosslinker. [3]
A Persulfide Analogue of the Nitrosothiol SNAP: Formation, Characterization and Reactivity. [4]
References:
[1] K.H.Pilgram, et al, J. Heterocycl. Chem., 1988, 25(1), pp 193-200.
[2] C.Starkennann, et al, J. Agric. Food Chem., 2011, 59(17), pp 9457-9465.
[3] R.Saxena, et al, Int. J. Pharm. Pharm. Sci., 2012, 4(Suppl. 4), pp 557-559.
[4] I.Artaud, et al, Chembiochem., 2014, 15(16), pp 2361-2364.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
Legal Information
Danger
H226,H314
P280,P305+P351+P338,P310
2930909899
UN 2920 3(8)/PG II

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