Cyclopropylboronic acid

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem CID
Reaxys RN
Cyclopropaneboronic acid, Cyclopropylboranediol
Non-Fluorochemicals
KUMI0F76
411235-57-9

PubChem ID

Reax
MFCD04038750

PubChem ID
2760897
9385789
image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay
Appearance
Melting Point
Packaging
Storage
Cyclopropylboronic acid
C3H7BO2
85.90
≥98%(GC)
White to Pale yellow Solid
90-95°C
5g,10g,25g,50g,100g,250g,500g and 1kg
Store at room temperature
Cyclopropylboronic acid (also name as Cyclopropaneboronic acid, Cyclopropylboranediol) is an organobornic acid commonly used as reagent in efficient Suzuki-type coupling reactions with a range of substrates, such as aryl and heteroarybromides, Azoles, Amides, Sulfonamides and Pridinols.
Cyclopropylboronic acid: synthesis and Suzuki cross-coupling reactions. [1]
Copper-Mediated N-Cyclopropylation of Azoles, Amides, and Sulfonamides by Cyclopropylboronic Acid. [2]
Microwave-assisted N-cyclopropylation of pyridinols with cyclopropyl boronic acid. [3]
Facile synthesis of aryl(het)cyclopropane catalyzed by palladacycle. [4]
References:
[1] D.J.Wallace, et al, Tetrahedron Lett., 2002, 43(39), pp 6987-6990.
[2] S.Benard, et al, J. Org. Chem., 2008, 73(16), pp 6441-6444.
[3] Y.B.Tambe, et al, Synth. Commun., 2012, 42, pp 1341-1348.
[4] M.Zhang, et al, Tetrahedron, 2012, 68(3), pp 900-905.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
Legal Information
Warning
H315,H319,H335
P264,P302+P352,P304+P340,P305+P351+P338,P332+P313,P337+P313
2931900090
NONH for all modes of transport.

1. Product Specification
2. Safety Data Sheet
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