(S)-(-)-2-Methyl-2-propanesulfinamide

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem CID
Reaxys RN
(S)-2-methylpropane-2-sulfinamide
Non-Fluorochemicals, Reagents for synthesizing chiral amines
KUMI0F370
343338-28-3

PubChem ID

Reax
MFCD05861480

PubChem ID
11355477
8973757
image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay
Appearance
Melting Point
Packaging
Storage
(S)-(-)-2-Methyl-2-propanesulfinamide
C4H11NOS
121.20
≥99%(99%ee)
White to Off-White Solid
97-101°C
5g,10g,25g,50g,100g,250g,500g and 1kg
Store at room temperature
(S)-(-)-2-Methyl-2-propanesulfinamide (also named as (S)-2-methylpropane-2-sulfinamide) is typically used as reagent for synthesizing chiral amines.
Asymmetric Synthesis of α,α-Difluoro-β-amino Acid Derivatives from Enantiomerically Pure N-tert-Butylsulfinimines. [1]
Highly Stereoselective Addition of Organometallic Reagents to N-tert-Butanesulfinyl Imines Derived from 3- and 4-Substituted Cyclohexanones. [2]
A Room-Temperature Protocol for the Rhodium(I)-Catalyzed Addition of Arylboron Compounds to Sulfinimines. [3]
Use of α-Chlorinated N-(tert-Butanesulfinyl)imines in the Synthesis of Chiral Aziridines. [4]
S-Chiral Sulfinamides as Highly Enantioselective Organocatalysts. [5]
Diastereoselective Synthesis of 2-Phenyl-3-(trifluoromethyl)piperazines as Building Blocks for Drug Discovery. [6]
Stereocontrolled Synthesis of a Potential Transition-State Inhibitor of the Salicylate Synthase MbtI from Mycobacterium tuberculosis. [7]
References:
[1] D.D.Staas, et al, J. Org. Chem., 2002, 67(23), pp 8276-8279.
[2] J.P.McMahon, et al, Org. Lett., 2004, 6(10), pp 1645-1647.
[3] Y.Bolshan, et al, Org. Lett., 2005, 7(8), pp 1481-1484.
[4] B.Denolf, et al, Org. Lett., 2006, 8(14), pp 3129-3132.
[5] D.Pei, et al, Org. Lett., 2006, 8(25), pp 5913-5915.
[6] M.Sanchez-Rosello, et al, 2014, 79(12), pp 5887-5894.
[7] Z.Liu, et al, J. Org. Chem., 2015, 80(13), pp 6545-6552.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
Legal Information
Not classified as a hazardous substance or mixture


2930909899
NONH for all modes of transport.

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