CuC2F5 is a new, low-cost and operationally simple reagent,which has successfully applied to two types of pentafluoroethylations with arylboronic acids and aryl bromides to provide the pentafluoroethylated aromatic products in good-to-excellent yields, including large scale operations.
Direct synthesis of pentafluoroethyl copper from pentafluoropropionate as an economical C2F5 source: Application to pentafluoroethylation of arylboronic acids and aryl bromides. [1]
Reference:
[1] H.Serizawa et al, Org. Lett., 2014, 16(13), pp 3456–3459.
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