Sodium Bromodifluoroacetate

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem SID
Reaxys RN
Bromodifluoroacetic acid sodium salt
Trifluoromethylating Reagents,Difluorocarbene Precursor
KUMI2F26
84349-27-9
MFCD04038355
253660024
8229431
image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay(Analysis Method)
Appearance
Melting Point
Packaging
Storage
Sodium Bromodifluoroacetate
C2BrF2NaO2
196.91
≥98.0%(HPLC)(T)
White to Light yellow Solid
146ºC
1g,5g,10g and 50g
Store at room temperature
Trifluoromethoxylating Reagent,Trifluoroethylating Reagent,Difluoromethylating Reagent.
Sodium bromodifluoroacetate: a difluorocarbene source for the synthesis of gem-difluorocyclopropanes.[1]
Copper-Catalyzed Decarboxylative Trifluoromethylation of Allylic Bromodifluoroacetates.[2]
Highly Controlled Ring-Opening of Siloxydifluorocyclopropanes: A Versatile Route to Cyclic Fluoroketones.[3]
The Reactivity of Difluorocarbene with Hydroxylamines: Synthesis of Carbamoyl Fluorides.[4]
References:
[1] K. Oshiro, Y. Morimoto, H. Amii, Synlett 2010, 2080.
[2] Ambler, B. R. et al.Org. Lett.2013,15, 5578.
[3] Y.Kageshima et al.Synlett 2015; 26(01): 63-66.
[4] B.Hannah et al.Advanced Synthesis and Catalysis, 2016 ,  vol. 358,  # 14  p. 2293 - 2299.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
Legal Information
Warning
H315,H319,H335
P261,P271,P280
2915.90.5050
NONH for all modes of transport

1. Product Specification
2. Safety Data Sheet
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