[Bis(trifluoroacetoxy)iodo]pentafluorobenzene

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem CID
Reaxys RN
Pentafluoro[bis(trifluoroacetoxy)iodo]benzene, FPIFA
Trifluoromethylating Reagents, Oxidizing Reagents
KUMIAF03
14353-88-9
MFCD00191612
626316
2030069
image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay
Appearance
Melting Point
Packaging
Storage
[Bis(trifluoroacetoxy)iodo]pentafluorobenzene
C10F11IO4
519.99
≥97%
White to Light yellow Solid
118-120°C
5g,10g,25g,50g,100g,250g and 500g
Store at room temperature
[Bis(trifluoroacetoxy)iodo]pentafluorobenzene (also named as FPIFA) is a scalable,operationally simple and radical reagent for decarboxylative trifluoromethylation of (hetero)arenes under photoredox catalysis has been developed.
Mild carbon–carbon bond cleavage of carbonyl compounds using pentafluoroiodobenzene bis(trifluoroacetate). [1]
Mild oxidative cleavage of alkynes using [bis(trifluoroacetoxy)iodo]pentafluorobenzene. [2]
Visible-Light Photoredox Decarboxylation of Perfluoroarene Iodine(III) Trifluoroacetates for C–H Trifluoromethylation of (Hetero)arenes. [3]
References:
[1] R.M.Moriarty, et al, J. Chem. Soc. Chem. Commun., 1987, 0, pp 202-203.
[2] R.M.Moriarty, et al, J. Org. Chem., 1988, 53(26), pp 6124-6125.
[3] B.Yang, et al, ACS Catal., 2018, 8(4), pp 2839-2843.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
Legal Information
Danger
H315,H319,H335
P280,P305+P351+P338,P310
2915907090
UN 1759 8/PG II

1. Product Specification
2. Safety Data Sheet
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