Methyl 5-(trifluoromethyl)-1H-pyrrole-2-carboxylate is an important building block for the synthesis of numerous trifluoromethylated heterocycles widely applied in pharmaceuticals, agrochemicals and material sciences.
Trifluoromethylation of heterocycles via visible light photoredox catalysis. 
Rapid Trifluoromethylation and Perfluoroalkylation of Five‐Membered Heterocycles by Photoredox Catalysis in Continuous Flow. 
Metal-Free Photocatalytic Radical Trifluoromethylation Utilizing Methylene Blue and Visible Light Irradiation. 
Mechanisms and applications of cyclometalated Pt(II) complexes in photoredox catalytic trifluoromethylation. 
Graphitic Carbon Nitride Polymer as a Recyclable Photoredox Catalyst for Fluoroalkylation of Arenes. 
Continuous Flow Homolytic Aromatic Substitution with Electrophilic Radicals: A Fast and Scalable Protocol for Trifluoromethylation. 
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