Tert-butyl 2-(trifluoromethyl)prop-2-enoate

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem CID
Reaxys RN
Tert-Butyl2-(trifluoromethyl)acrylate, TFMA-B
Trifluoromethyl Building Blocks
KUMI3F102
105935-24-8
MFCD04038275
2782282
9389472
image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay
Appearance
Boiling Point
Packaging
Storage
Tert-butyl 2-(trifluoromethyl)prop-2-enoate
C8H11F3O2
196.17
≥98%
Colorless to Light-yellow Liquid
120°C
5g,10g,25g,50g,100g,250g and 500g
Store at room temperature
Tert-butyl 2-(trifluoromethyl)prop-2-enoate is an important building block for the synthesis of various trifluoromethyl-substituted organic compounds in material sciences, e.g. anti-reflection film materials using fluorine-containing copolymers.
Carbon–carbon bond formation by radical addition of α-trifluoromethylacrylate with cyclic ethers. [1]
Expeditious Synthesis of Trifluoromethylated Heterocycles: Noncatalytic 1,3-Dipolar Cyclization of Azomethine Imines with (α-Trifluoromethyl)acrylates. [2]
Synthesis and polymerization of novel fluoroalkyl 2‐trifluoromethylacrylate possessing tetrahydrofuran moiety. [3]
Bis(formylphenolato)cobalt(II)-Mediated Alternating Radical Copolymerization of tert-Butyl 2-Trifluoromethylacrylate with Vinyl Acetate. [4]
References:
[1] A.Hosoya, et al, J. F. Chem., 2008, 129(2), pp 91-96.
[2] S.Ogawa, et al, Synthesis, 2010, 19, pp 3274-3281.
[3] A.Hosoya, et al, J. Polym. Sci. A, 2011, 49(23), pp 5129-5131.
[4] S.Banerjee, et al, Polymers, 2017, 9(12), pp 702-712.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
Legal Information
Warning
H315,H319,H335
P264,P271,P280,P305+P351+P338
29161200
NONH for all modes of transport

1. Product Specification
2. Safety Data Sheet
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