Trifluoromethyl(1,10-Phenanthroline)copper(I)

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem SID
Reaxys RN
Hartwig Trifluoromethylation reagent, (Phen)CuCF3, Trifluoromethylator
Trifluoromethylating Reagents
KUMI3F18
1300746-79-5
MFCD19690901
329767921
22327207
image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay
Appearance
Melting Point
Packaging
Storage
Trifluoromethyl(1,10-Phenanthroline)copper(I)
C13H8CuF3N2
312.76
≥95%(NMR)
Light Red to Dark Red Solid
108-224°C
5g,10g,50g,100g and 500g
Store at room temperature ( air & moisture sensitive)
Trifluoromethyl(1,10-Phenanthroline)copper(I) (also named as Hartwig trifluoromethylation reagent, (Phen)CuCF3, trifluoromethylator) is a new, versatile, easily handled, thermally stable, single-component reagent for the trifluoromethylation of various aryls and heteroaryls.
A broadly applicable copper reagent for trifluoromethylations and perfluoroalkylations of aryl iodides and bromides. [1]
Copper-Mediated Perfluoroalkylation of Heteroaryl Bromides with (phen)CuRF. [2]
Trifluoromethylation of Arylsilanes with [(phen)CuCF3]. [3]
References:
[1] H.Morimoto, et al, Angew Chem Int Ed Engl., 2011, 50(16), pp 3793-3798.
[2] M.G.Mormino, et al, Org.Lett., 2014, 16(6), pp 1744–1747.
[3] J.Morstein, et al, Angew. Chem. Int. Ed. Engl., 2016, 55(28), pp 8054-8057.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
Legal Information
Warning
H302+H312,H315,H319
P280,P305+P351+P338
2934999090
NONH for all modes of transport
Trifluoromethylator is a registered trademark of Catylix, Inc.
1. Product Specification
2. Safety Data Sheet
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