tert-Butyl carbamate

Synonym
Product Category
Product Code
CAS Number
MDL Number
Pubchem CID
Reaxys RN 3582735
Carbamic Acid tert-Butyl Ester,Boc-NH2 ,Boc-amide
Bridge to Biologics, Protecting Reagents
KUMI0F471
4248-19-5
MFCD00007962
77922
1744500
image-155171-Trimethyl(trifluoromethyl)silane_reagent.png
Chemical Name
Molecular Formula
Molecular Weight
Assay
Appearance
Melting Point
Packaging
Storage
tert-Butyl carbamate
C5H11NO2
117.15
≥99%
White to Off-white Solid
105-108°C
5g,10g,50g,100g,500g, 1kg and 25kg
Store at 2-8°C temp.
 tert-Butyl carbamate (also named as Carbamic Acid tert-Butyl Ester,Boc-NH2 ,Boc-amide) is mainly used in palladium-catalyzed synthesis of N-Boc-protected anilines. It was also used in the synthesis of tetrasubstituted pyrroles, functionalized with ester or ketone groups at C-3 position.
 Room-temperature Pd-catalyzed amidation of aryl bromides using tert-butyl carbamate. [1]
 Pd-catalyzed amidation of aryl(Het) halides with tert-butyl carbamate. [2]
 References:
[1] S.Bhagwanth, et al, J. Org. Chem., 2009, 74(12), pp 4634-4637.
[2] L.Qin, et al, Tetrahedron Lett., 2010, 51(33), pp 4445-4448.
Signal Word
Hazard Statements
Precautionary Statements
HS Code
RIDADR
Legal Information
Not regulated
 
 
29241900
NONH for all modes of transport

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